Under the custom schedules tab you can create different settings to each shipping method
Schedule based on: Settings applied based on shipping method
Enable/Disable Delivery fields: Disable/Enable for specific shipping method
Shipping Method: Shipping Method to apply this setting
Customize Days and Time on specific weekdays
Weekday: The weekdays to apply this settings
Enable/Disable Delivery Time: Enable timeslots on checkout
Timeslots: Choose if want to generate the timeslots based on a given time and duration, or if want to specify each timeslots manually
Timeslot Begin – End: Begin – end for generating timeslots
Timeslot duration: Duration in minutes for each generated timeslot